Free Product Recovery

Introduction to Free Product Recovery Principles

Many heavily contaminated sites contain free products within the soils and water table. Removal of this free product is essential in remediating contaminated sites, as free-phase contaminants represent the largest reservoir of pollutants, allowing contaminants to migrate and cause further pollution.

There are two types of free products:

  • Light Non-Aqueous Phase Liquids (LNAPL): Contaminants that are less dense than water, floating on the water table surface.
  • Dense Non-Aqueous Phase Liquids (DNAPL): Contaminants denser than water, sinking to the bottom of the water table and resting on impermeable surfaces, such as clays and bedrock.

Free-phase product recovery is often combined with other treatment processes, such as soil vapour extraction (SVE), dual-phase extraction, ex-situ treatments, and bioremediation. It is rarely undertaken alone, except in the least sensitive environmental settings. Depending on physical properties, free product can be recovered as a liquid or vapour, and recovery can be enhanced through methods such as steam injection or surfactant flushing.

Contaminants Suited for Free Product Recovery

Free product recovery is applicable to a wide range of chemicals. Common free product contaminants include:

  • Light Non-Aqueous Phase Liquids (LNAPL)
  • Diesel Range Organics (DRO)
  • Petroleum Range Organics (PRO)
  • Kerosene
  • Dense Non-Aqueous Phase Liquids (DNAPL)
  • Creosote
  • Chlorinated Solvents
  • Coal Tars
  • Polychlorinated Biphenyls (PCBs)

Free Product Recovery Plant Description

Free-phase product recovery can be conducted as an ex-situ method from open excavation, using floating or sinking skimmers, or via in-situ remediation methods. This can involve excavating or installing wells or trenches to access the free product. Skimmer or top-loading total fluid pumps are used to collect LNAPL free product, or product-only for low-intensity recovery where time is not a critical factor. Bottom-loading total fluid pumps are applied for DNAPL recovery. Collected free product is filtered and stored onsite before being sent off-site for recycling at a licensed facility. Volatile free products (e.g., petrol or xylene) can be volatilised using air sparging and recovered as vapour through dual-phase or high-vacuum systems.

Key Components of Free Product Recovery Equipment

Free product recovery equipment typically includes:

  • Abstraction System (e.g., high-vacuum system)
  • Abstraction Pumps (pneumatic pumps, skimmer pumps, etc.)
  • Free Product Storage Tank
  • Secure Storage Area for Free Product
  • Control Systems
  • Compressor (for pneumatic pumps)
  • Pipework
  • Oil-Water Separator

Example of Free Product Recovery Application

VertaseFLI has designed and operated numerous free-phase product recovery systems for both open excavation recovery and in-situ systems. One such system was deployed to remove LNAPL free product from a disused aluminium casting foundry in preparation for the site’s redevelopment.

The free product recovery system involved drilling 32 abstraction and monitoring wells, and using pneumatic top-loading total fluid and product-only pumps to remove the free product. The abstracted free product was filtered through a tilted plate oil-water separator and stored onsite, ready for off-site recycling.

This system ran automatically, requiring periodic maintenance checks over a 68-week period. A total of 16,800 litres of free product was removed, the majority during the first 28 weeks of operation. Despite the duration of the remedial works, the compact design and in-situ remediation techniques used by VertaseFLI ensured that remediation did not impact the redevelopment schedule.

'Teamwork' by Richard Williams

Advantages and Limitations of Free Product Recovery

Advantages of Free Product Recovery

  • Large Contaminant Mass Recovery: Capable of removing a substantial contaminant mass in a short period.
  • Significant Plume Contaminant Reduction: Free product often constitutes over 99% of the plume contaminant mass.
  • Proven Effectiveness: Demonstrated success on UK contaminated sites.
  • In-Situ Application Possibility: Requires only a small area for unit setup, allowing for compact site operations.
  • Effective Contaminant Volume Reduction: Achieves significant reduction of contaminant volumes.

Limitations of Free Product Recovery

  • Residual Contaminant Treatment Requirement: Often requires further treatment to remove remaining contaminants (e.g., in-situ bioremediation).
  • Complex DNAPL Removal: Removal of DNAPL can be challenging due to the nature of the contaminants involved.

The Vertase team were always polite and professional, both on calls and on site. Our H&S team were very impressed by Vertase.

Jo McKay

Managing Consultant, Ramboll UK, DS Smith

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