Ex-Situ Bioremediation

Introduction to Ex-Situ Bioremediation Principles

Ex-situ bioremediation is a biological process in which excavated soil is placed in a lined above-ground treatment area and aerated following processing to enhance the degradation of organic contaminants by the indigenous microbial population. Under aerobic conditions, specific micro-organisms can utilise organic contaminants such as petroleum hydrocarbon mixtures, polycyclic aromatic hydrocarbons (PAH), phenols, cresols, and some pesticides as a source of carbon and energy, ultimately degrading them to carbon dioxide and water.

The native microbial populations are usually sufficient to break down the contamination, but it is common to assess the nutrient requirements and amend the basic nutrients and organic substrate of the soil if any of these elements are deficient or absent. Oxygen (i.e. air) is essential to allow the microbial population to develop cultures capable of sustaining degradation. Therefore, frequent aeration of the soil is an important element in maintaining the population.

Ex-Situ Bioremediation Methods

As a general rule, all but the most homogeneous excavated soils require processing before bioremediation techniques can be successfully applied. There are a number of different techniques and formats for biological treatment; however, the basic principle of introducing the correct soil oxygen, moisture, and nutrient conditions prevails.

Contaminants Suitable for
Ex-Situ Bioremediation

Ex-situ bioremediation can remediate a wide range of hydrocarbon contaminants, including but not limited to:

  • General hydrocarbons
  • Kerosene
  • Phenols
  • Cresols
  • Polycyclic aromatic hydrocarbons (PAHs)
  • Semi-volatile organic compounds
  • Diesel range hydrocarbons and lubricating oils
  • Straight-chain aliphatics

Non-chlorinated hydrocarbons within the carbon chain lengths C6 to C14 are readily treatable. Non-chlorinated hydrocarbons with carbon chain lengths C15-C32 are treatable but require longer time periods to degrade. Chlorinated hydrocarbons and other more complex chains can be degraded but require detailed assessment and analysis to determine suitability.

Ex-situ bioremidation service

Ex-Situ Bioremediation

The excavated soil is placed into a shaped pile between 1.5 and 2 meters in height and up to 6 meters wide in a lined area. The pile is aerated by periodically turning the windrows with specialised machinery, which can be excavator-mounted or self-propelled. Soil organic amendments and nutrients can be easily added to the windrows during turning to improve aeration and soil characteristics as required. This is often the most cost-effective method of ex-situ biological treatment.

Force-Vented Biopiles for Contaminant Control

Where more complex contaminants are present in the soils or treatment timescales are short, additional measures can be adopted to optimise the treatment process via forced ventilation.

The excavated soil is placed into a shaped pile up to 3 meters in height and 6 meters wide in a lined area. The pile is aerated either via a vacuum pump or air injection blower system to force oxygen into the biopile. The vapours generated in the biopile can be collected and treated onsite by granular activated carbon (GAC) or an air bio-filter to reduce emissions to the atmosphere. Biopiles can be constructed taller than windrows, requiring less space on-site. Additionally, the injection of air can be used to control bed temperature during winter if overwintering is required. It is also the preferred choice if particularly odorous or volatile contaminants are an issue.

Environmental Considerations for Ex-Situ Bioremediation

For all bioremediation techniques, an Environmental Permit is required from the Environment Agency (or for a limited number of smaller projects working in accordance with a Regulatory Position Statement). Any vapours and runoff (or “leachate”) from the soil need to be collected and treated appropriately during the works.

Treatment times range from 6 to 16 weeks depending on contamination, target concentrations, contaminant type, concentration, soil properties, and the time of year. Ambient temperature has a significant effect on bioremediation, with the best degradation rates occurring during the warmer summer months; cold winter weather can significantly slow and even halt biodegradation.

Advantages and Limitations of Ex-Situ Bioremediation

Advantages

  • Proven track record on UK-contaminated sites
  • Suitable for a wide range of contaminants
  • Suitability is relatively simple to assess from site investigation data
  • Flexible with respect to volumes (treated in excess of 250,000 tonnes in one season on some sites)

Limitations

  • Not applicable to heavy metal contamination or chlorinated hydrocarbons such as trichloroethylene (TCE)
  • Non-permeable soils require additional processing (clays, silts, etc.)
  • Can require large areas for treatment beds, making site size an important consideration
  • Contaminants must be aerobically biodegradable
  • Temperature, weather, and material-dependent limitations
It’s a personal and professional pleasure to work with Vertase, the people there are dedicated, knowledgeable and helpful in every way.

Lee Howard – GradIOSH & AIEMA

Group SHE Manager, Harron Homes

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